Mononuclear Molybdenum Oxohalide Complexes (Bu4N)[MoOCl4(H2O)] and (Bu4N)[MoOBr4(H2O)]: Synthesis and Crystal Structures

被引：0
|
作者：
Adonin, S. A. [1 ,2 ]
Udalova, L. I. [2 ]
Abramov, P. A. [1 ,2 ]
Sokolov, M. N. [1 ,3 ]
Fedin, V. P. [1 ,2 ]
机构：
[1] Russian Acad Sci, Siberian Branch, Nikolaev Inst Inorgan Chem, Novosibirsk 630090, Russia
[2] Novosibirsk State Univ, Novosibirsk 630090, Russia
[3] Kazan Volga Reg Fed Univ, Kazan, Russia
来源：
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2018年 / 44卷 / 11期
关键词：
molybdenum; halide complexes; heteroligand complexes; X-ray diffraction analysis; LIGANDS; OXOTETRABROMOMOLYBDENUM(V); PYRIDINE; HALIDES; CORE;
D O I：
10.1134/S1070328418110015
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The oxidation of K-3[MoCl6] with air oxygen in aqueous solutions of HX (X = Cl, Br) in the presence of n-tetrabutylammonium salts affords mononuclear heteroligand complexes (Bu4N)[MoOCl4(H2O)] (I) and (Bu4N)[MoOBr4(H2O)] (II). The complexes are characterized by X-ray diffraction analysis (CIF files CCDC nos. 1812657 (I) and 1812658 (II).
引用
收藏
页码：673 / 677
页数：5
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