Synthesis and crystal structure of [Co(phen)(H2O)4](SO4)⋅2(H2O)

被引：0
|
作者：
Hai-Liang Zhu
Yong-Jun Pan
Xian-Jiang Wang
Kai-Bei Yu
机构：
[1] Fuyang Normal College,Department of Chemistry
[2] Chinese Academy of Science,Chengdu Center of Analysis and Measurement
来源：
Journal of Chemical Crystallography | 2004年 / 34卷
关键词：
Synthesis; crystal structure; cobalt(II) complex; phenanthroline; hydrogen bonds; π–π stacking;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The title complex, [Co(phen)(H2O)4](SO4)⋅2(H2O) (phen = 1,10-phenanthroline) was prepared in aqua tert-butylperoxohydrogen solution. X-ray single crystal structure determination reveals that the complex consists of a phenanthrolinatocobalt(II)tetrahydrate dication, two uncoordinated water molecules and a sulfate anion. It crystallizes in the orthorhombic space group Pbca with a = 8.856(1), b = 18.318(3), c =21.918(5) Å, V = 3555.6(11) Å3. The coordination geometry at each cobalt(II) atom is a slightly distorted octahedron.
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页码：199 / 202
页数：3
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