Syntheses of six- and seven-membered nitrogen heterocycles from cyclic amino phosphnium salts

被引:0
|
作者
Sakai, T [1 ]
Ida, K [1 ]
Uchiyama, T [1 ]
Fujimoto, T [1 ]
Ohta, K [1 ]
Yamamoto, I [1 ]
Kakehi, A [1 ]
机构
[1] SHINSHU UNIV,FAC ENGN,DEPT CHEM & MAT ENGN,WAKASATO,NAGANO 380,JAPAN
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中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The cyclic aza-ylides, 2a, b, that are generated from 6- or 5-membered cyclic amino phosphonium salts, 1a, b, can react with various carbonyl compounds. The acyclic imine derivatives were obtained by the reaction of these cyclic aza-ylides with benzils, and these imine derivatives were treated with LDA to produce the tetrahydropyridine or tetrahydroazepine derivatives.
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页码:233 / 239
页数:7
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