Organocatalysis for new chiral fullerene-based materials

被引：12

作者：

Giron, Rosa M. ^{[1
]}

Reboredo, Silvia ^{[1
]}

Marco-Martinez, Juan ^{[1
]}

Filippone, Salvatore ^{[1
]}

Martin, Nazario ^{[1
,2
]}

机构：

[1] Univ Complutense, Fac Quim, Dept Quim Organ 1, E-28040 Madrid, Spain

[2] IMDEA Nanosci, E-28049 Madrid, Spain

来源：

FARADAY DISCUSSIONS | 2014年 / 173卷

基金：

欧洲研究理事会;

关键词：

PHOSPHINE-CATALYZED CYCLOADDITION; CHEMISTRY; CARBON; DERIVATIVES;

D O I：

10.1039/c4fd00065j

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The cycloaddition reaction of 3-alkynoates to fullerenes has been studied under different experimental conditions and phosphines in the presence of a base which is responsible for the previous isomerization to the corresponding allenoate. The versatility of this reaction allows chiral fullerenes to be obtained at will, thus opening up a new avenue in the use of enantiomerically pure carbon nanostructures in materials science.

引用

页码：311 / 322

页数：12

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