Organocatalysis for new chiral fullerene-based materials

被引：12
|
作者：
Giron, Rosa M. [1 ]
Reboredo, Silvia [1 ]
Marco-Martinez, Juan [1 ]
Filippone, Salvatore [1 ]
Martin, Nazario [1 ,2 ]
机构：
[1] Univ Complutense, Fac Quim, Dept Quim Organ 1, E-28040 Madrid, Spain
[2] IMDEA Nanosci, E-28049 Madrid, Spain
来源：
FARADAY DISCUSSIONS | 2014年 / 173卷
基金：
欧洲研究理事会;
关键词：
PHOSPHINE-CATALYZED CYCLOADDITION; CHEMISTRY; CARBON; DERIVATIVES;
D O I：
10.1039/c4fd00065j
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The cycloaddition reaction of 3-alkynoates to fullerenes has been studied under different experimental conditions and phosphines in the presence of a base which is responsible for the previous isomerization to the corresponding allenoate. The versatility of this reaction allows chiral fullerenes to be obtained at will, thus opening up a new avenue in the use of enantiomerically pure carbon nanostructures in materials science.
引用
收藏
页码：311 / 322
页数：12
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