Organometallic alkylthiolate-bridged manganese cubanes

被引：14
|
作者：
ReyesLezama, M [1 ]
Toscano, RA [1 ]
ZunigaVillarreal, N [1 ]
机构：
[1] UNIV NACL AUTONOMA MEXICO,INST QUIM,COYOACAN 04510,DF,ARGENTINA
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1996年 / 517卷 / 1-2期
关键词：
manganese; thiolates; cubanes; pentadienyl complexes;
D O I：
10.1016/0022-328X(96)06111-6
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The thermal reaction of tricarbonyl-eta(5)-pentadienylmanganese 1, with mercaptans RSH leads to the corresponding tetramers [MnSR(CO)(3)](4) (R = phenyl 2, furfuryl 3, and phenethyl 4). Synthetic and spectroscopic aspects, as well as the single crystal X-ray structure of 3, are discussed.
引用
收藏
页码：19 / 23
页数：5
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