COMPLEXES OF IRON AND MANGANESE WITH OXYGEN-BRIDGED, SULFUR-BRIDGED, AND METHYLENE-BRIDGED DISTIBINES AND WITH CHLORODIPHENYLSTIBINE AS LIGANDS

被引：5
|
作者：
GRAF, N [1 ]
WIEBER, M [1 ]
机构：
[1] UNIV WURZBURG,INST ANORGAN CHEM,AM HUBLAND,D-97074 WURZBURG,GERMANY
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1993年 / 619卷 / 12期
关键词：
DICARBONYLBIS(TRIPHENYLPHOSPHITE)(STIBINE)IRON COMPLEXES; BIS[DICARBONYLBIS(TRIPHENYLPHOSPHITE)IRON](STIBINE) COMPLEXES; DICARBONYL ETA(5)-METHYLCYCLOPENTADIENYL)(STIBINE)MANGANESE COMPLEXES; BIS[DICARBONYL-ETA(5)-METHYLCYCLOPENTADIENYL)MANGANESE](STIBINE) COMPLEXES;
D O I：
10.1002/zaac.19936191215
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The photochemical reaction of (CO)3Fe[P(OPh)3]2 and of MeCpMn(CO)3 with the stibines Ph2SbCl and (Ph2Sb)2X (X = O, S and CH2) yields mononuclear complexes (CO)2[P(OPh)3]2FeL and MeCp(CO)2MnL (L = Ph2SbCl, (Ph2Sb)2X) and the stibine bridged binuclear complexes (CO)2[P(OPh)3]2Fe{(Ph2Sb)2X}Fe(CO)2[P(OPh)3]2 and MeCP(CO)2Mn{(Ph2Sb)2X}Mn(CO)2MeCp.
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页码：2061 / 2065
页数：5
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