Synthesis of (+/-)-curcumene ether

被引：0
|
作者：
Vickers, TD [1 ]
Keay, BA [1 ]
机构：
[1] Univ Calgary, Dept Chem, Calgary, AB T2N 1N4, Canada
来源：
SYNLETT | 2003年 / 09期
关键词：
total synthesis; intramolecular Heck reaction; spiro compounds; lactones; natural products;
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A 9 step synthesis of (+/-)-curcumene ether is described starting from 5-bromo-2-methyl-2-pentene and 2-amino-5-methylphenol in 7% overall yield using an intramolecular Heck reaction as the key transformation to generate a stereogenic quaternary center.
引用
收藏
页码：1349 / 1351
页数：3
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