Synthesis of (+/-)-curcumene ether

被引：0

作者：

Vickers, TD ^{[1
]}

Keay, BA ^{[1
]}

机构：

[1] Univ Calgary, Dept Chem, Calgary, AB T2N 1N4, Canada

来源：

SYNLETT | 2003年 / 09期

关键词：

total synthesis; intramolecular Heck reaction; spiro compounds; lactones; natural products;

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A 9 step synthesis of (+/-)-curcumene ether is described starting from 5-bromo-2-methyl-2-pentene and 2-amino-5-methylphenol in 7% overall yield using an intramolecular Heck reaction as the key transformation to generate a stereogenic quaternary center.

引用

页码：1349 / 1351

页数：3

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