Asymmetric hydrogenation of imines catalysed by carboxylato(diphosphine)iridium(III) complexes

被引：57
|
作者：
Sablong, R [1 ]
Osborn, JA [1 ]
机构：
[1] UNIV STRASBOURG 1,INST LE BEL,LAB CHIM MET TRANSIT & CATALYSE,CNRS,UNITE RECH ASSOCIEE 424,F-67070 STRASBOURG,FRANCE
来源：
TETRAHEDRON-ASYMMETRY | 1996年 / 7卷 / 11期
关键词：
D O I：
10.1016/0957-4166(96)00397-7
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The synthesis of three new families of monomeric carboxylato(diphosphine)iridium(III) complexes is described (e.g. diphosphine = diop, binap, bdpp). Some of these complexes catalyse the asymmetric hydrogenation of prochiral imines to amines in good activity and enantioselectivity. Copyright (C) 1996 Elsevier Science Ltd
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收藏
页码：3059 / 3062
页数：4
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