Asymmetric hydrogenation of imines catalysed by carboxylato(diphosphine)iridium(III) complexes

被引：57
|
作者：
Sablong, R [1 ]
Osborn, JA [1 ]
机构：
[1] UNIV STRASBOURG 1,INST LE BEL,LAB CHIM MET TRANSIT & CATALYSE,CNRS,UNITE RECH ASSOCIEE 424,F-67070 STRASBOURG,FRANCE
来源：
TETRAHEDRON-ASYMMETRY | 1996年 / 7卷 / 11期
关键词：
D O I：
10.1016/0957-4166(96)00397-7
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The synthesis of three new families of monomeric carboxylato(diphosphine)iridium(III) complexes is described (e.g. diphosphine = diop, binap, bdpp). Some of these complexes catalyse the asymmetric hydrogenation of prochiral imines to amines in good activity and enantioselectivity. Copyright (C) 1996 Elsevier Science Ltd
引用
收藏
页码：3059 / 3062
页数：4
相关论文
共 50 条
  • [21] Amine(imine)diphosphine Iron Catalysts for Asymmetric Transfer Hydrogenation of Ketones and Imines
    Zuo, Weiwei
    Lough, Alan J.
    Li, Young Feng
    Morris, Robert H.
    SCIENCE, 2013, 342 (6162) : 1080 - 1083
  • [22] Asymmetric Hydrogenation of Cyclic Imines Catalyzed by Chiral Spiro Iridium Phosphoramidite Complexes for Enantioselective Synthesis of Tetrahydroisoquinolines
    Xie, Jian-Hua
    Yan, Pu-Cha
    Zhang, Qian-Qian
    Yuan, Ke-Xing
    Zhou, Qi-Lin
    ACS CATALYSIS, 2012, 2 (04): : 561 - 564
  • [23] Synthesis of enantiopure iridium(I) and iridium(III) pybox complexes and their application in the asymmetric transfer hydrogenation of ketones
    Paredes, Paloma
    Diez, Josefina
    Gamasa, M. Pilar
    ORGANOMETALLICS, 2008, 27 (11) : 2597 - 2607
  • [24] Asymmetric hydrogenation of imines catalyzed by iridium complexes with phosphine-phosphite ligands:: importance of backbone flexibility
    Vargas, S
    Rubio, M
    Suárez, A
    Pizzano, A
    TETRAHEDRON LETTERS, 2005, 46 (12) : 2049 - 2052
  • [25] Efficient transfer hydrogenation of alkynes and alkenes with methanol catalysed by hydrido(methoxo)iridium(III) complexes
    Tani, K
    Iseki, A
    Yamagata, T
    CHEMICAL COMMUNICATIONS, 1999, (18) : 1821 - 1822
  • [26] Cyclometalated Iridium Complexes as Highly Active Catalysts for the Hydrogenation of Imines
    Tang, Weijun
    Lau, Chunho
    Wu, Xiaofeng
    Xiao, Jianliang
    SYNLETT, 2014, 25 (01) : 81 - 84
  • [27] Methylaluminoxane as an Alternative for BArF in the Iridium-Catalyzed Asymmetric Hydrogenation of Imines
    Mrsic, Natasa
    Panella, Lavinia
    IJpeij, Edwin G.
    Minnaard, Adriaan J.
    Feringa, Ben L.
    de Vries, Johannes G.
    CHEMCATCHEM, 2011, 3 (07) : 1139 - 1142
  • [28] Highly efficient hydrogenation of carbon dioxide to formate catalyzed by iridium(III) complexes of imine-diphosphine ligands
    Liu, Chong
    Xie, Jian-Hua
    Tian, Gui-Long
    Li, Wei
    Zhou, Qi-Lin
    CHEMICAL SCIENCE, 2015, 6 (05) : 2928 - 2931
  • [29] Recent advances in iridium-catalysed asymmetric hydrogenation of unfunctionalised olefins
    Roseblade, Stephen J.
    Pfaltz, Andreas
    COMPTES RENDUS CHIMIE, 2007, 10 (03) : 178 - 187
  • [30] Asymmetric hydrogenation of imines
    Dieguez, Montserrat
    Claver, Carmen
    Margalef, Jessica
    METAL-CATALYZED ASYMMETRIC HYDROGENATION: EVOLUTION AND PROSPECT, 2021, 68 : 205 - 289
12345