Synthesis and Properties of C,N-Chelated Carbene Complexes of Palladium(II) with 2-Aminobenzo[d]thiazole Fragment

被引:4
|
作者
Mikherdov, A. S. [1 ]
Baikov, S. V. [1 ]
Proskurina, I. K. [2 ]
Shetnev, A. A. [2 ]
Kotov, A. D. [2 ]
机构
[1] St Petersburg State Univ, Univ Skaya Nab 7-9, St Petersburg 199034, Russia
[2] KD Ushinskii Yaroslavl State Pedag Univ, M Dorogov Ctr Transfer Pharmaceut Technol, Yaroslavl, Russia
基金
俄罗斯科学基金会;
关键词
acyclic diaminocarbene complexes; palladium chelate complexes; isocyanide ligands; antimicrobial activity; benzo[d]thiazole-2-amines; ACYCLIC DIAMINOCARBENE COMPLEXES; COPPER-FREE; EFFICIENT CATALYSTS; ADC COMPLEXES; SONOGASHIRA; LIGANDS; ISOCYANIDES; PLATINUM(II); PRECATALYSTS; ISONITRILES;
D O I
10.1134/S1070363219100128
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The reaction of bis(cyclohexylisocyanide) complex of Pd(II) with substituted benzo[d]thiazole-2-amines in the presence of triethanolamine as the base has lead to the formation of deprotonated C,N-chelated carbene complexes with a structure similar to that described previously for the products of the reaction with unsubstituted benzo[d]thiazole-2-amine. The complexes have been isolated and characterized using high-resolution mass spectrometry, IR and NMR spectroscopy (H-1, C-13{H-1}, H-1-H-1 COSY, H-1-H-1 NOESY, H-1-C-13 HSQC, H-1-C-13 HMBC). The resulting complexes have exhibited moderate antibacterial activity against sensitive strains of gram-negative bacteria E. coli (C600) and P. fluorescens (P218), gram-positive bacteria S. aureus (ATCC-25923) and B. subtillis (B-3142D) as well as fungi C. albicans (401/NCTC-885-653).
引用
收藏
页码:2062 / 2068
页数:7
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