Metal-Free Visible-Light-Mediated Oxidative Cross-Coupling of Thiols with P(O)H Compounds Using Air as the Oxidant

被引：127

作者：

Sun, Jian-Guo ^{[1
]}

Yang, Hua ^{[1
]}

Li, Ping ^{[1
]}

Zhang, Bo ^{[1
]}

机构：

[1] China Pharmaceut Univ, State Key Lab Nat Med, 24 Tongjia Xiang, Nanjing 210009, Jiangsu, Peoples R China

来源：

ORGANIC LETTERS | 2016年 / 18卷 / 19期

关键词：

SECONDARY PHOSPHINE OXIDES; C-H ARYLATION; PHOTOREDOX CATALYSIS; SINGLET OXYGEN; PROMOTED SYNTHESIS; NICKEL CATALYSIS; ARYL; PHOSPHONATES; THIOPHOSPHATES; AMINES;

D O I：

10.1021/acs.orglett.6b02563

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Visible light along with 5 mol % of rose bengal, catalyzes the direct S-P(O) coupling between thiols and P(O) H compounds in the presence of air as the green oxidant. The, protocol is operationally simple and amenable to gram-scale synthesis. A variety of S-P(O) coupling products can be readily. prepared in moderate to excellent yields. The reaction features good functional-group tolerance, operational simplicity, and excellent practicality.

引用

页码：5114 / 5117

页数：4

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