A facile and efficient procedure for the deoxygenation of sulfoxides to sulfides with the HfCl4/Zn system

被引：8

作者：

Yoo, Byung Woo ^{[1
]}

Yu, Bo Ran ^{[1
]}

Yoon, Cheol Min ^{[1
]}

机构：

[1] Korea Univ, Dept Adv Mat Chem, Sejong 339700, South Korea

来源：

JOURNAL OF SULFUR CHEMISTRY | 2015年 / 36卷 / 04期

关键词：

sulfoxide; zinc; hafnium(IV) chloride; sulfide; deoxygenation; AMINE-N-OXIDES; MILD; REDUCTION; SELENOXIDES;

D O I：

10.1080/17415993.2015.1031234

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Treatment of sulfoxides with the HfCl4/Zn system in acetonitrile at room temperature has been shown to provide the corresponding sulfides in high yields. This new methodology is highly chemoselective, tolerating several functional groups such as -Br, -Cl, -OCH3, -CHO and double bond.

引用

页码：358 / 363

页数：6

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