A facile and efficient procedure for the deoxygenation of sulfoxides to sulfides with the HfCl4/Zn system

被引：8
|
作者：
Yoo, Byung Woo [1 ]
Yu, Bo Ran [1 ]
Yoon, Cheol Min [1 ]
机构：
[1] Korea Univ, Dept Adv Mat Chem, Sejong 339700, South Korea
来源：
JOURNAL OF SULFUR CHEMISTRY | 2015年 / 36卷 / 04期
关键词：
sulfoxide; zinc; hafnium(IV) chloride; sulfide; deoxygenation; AMINE-N-OXIDES; MILD; REDUCTION; SELENOXIDES;
D O I：
10.1080/17415993.2015.1031234
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Treatment of sulfoxides with the HfCl4/Zn system in acetonitrile at room temperature has been shown to provide the corresponding sulfides in high yields. This new methodology is highly chemoselective, tolerating several functional groups such as -Br, -Cl, -OCH3, -CHO and double bond.
引用
收藏
页码：358 / 363
页数：6
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