(E)-5-(2-Chlorophenyl)-7-ethyl-2-oxo-2,3-dihydro-1H-thieno[2,3-e][1,4]diazepin-4-ium 2,4,6-trinitrophenolate

被引：1

作者：

Betz, Richard ^{[1
]}

Gerber, Thomas ^{[1
]}

Hosten, Eric ^{[1
]}

Dayananda, Alaloor S. ^{[2
]}

Yathirajan, Hemmige S. ^{[2
]}

Ramesha, A. R. ^{[3
]}

机构：

[1] Nelson Mandela Metropolitan Univ, Dept Chem, Port Elizabeth, South Africa

[2] Univ Mysore, Dept Studies Chem, Mysore 570006, Karnataka, India

[3] RL Fine Chem, Bangalore 560064, Karnataka, India

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2012年 / 68卷

关键词：

GRAPH-SET ANALYSIS; CRYSTALS; PATTERNS;

D O I：

10.1107/S1600536812002607

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title molecular salt, C15H14ClN2OS+center dot C6H2N3O7-, protonation occurred on the double-bonded N atom. One of the nitro groups shows slight disorder over two orientations, with an occupancy ratio of 0.91:0.09. In the crystal, classical N-H center dot center dot center dot O hydrogen bonds, as well as C-H center dot center dot center dot O contacts connect the components into a three-dimensional network. The seven-membered ring adopts a boat-like conformation. The least-squares plane defined by its non-H atoms encloses an angle of 38.99 (6)degrees with the benzene ring bonded to it.

引用

页码：O516 / U1668

页数：13

共 50 条

[1] Temperature-Dependent Ordering of the Methyl Group in the Crystal Structure of 5-(2-Chlorophenyl)-7-ethyl-1H-thieno [2,3-E] [1,4]diazepin-2(3H)-one
Dutkiewicz, Grzegorz
Kubicki, Maciej
Dayananda, Alaloor S.
Yathirajan, Hemmige S.
Ramesha, Andagar R.
CRYSTALS, 2012, 2 (03): : 1347 - 1356
[2] SYNTHESIS AND PHARMACOLOGICAL EVALUATION OF 2,3-DIHYDRO-H-1 THIENO[2,3-E][1,4]DIAZEPINES
TINNEY, FJ
SANCHEZ, JP
NOGAS, JA
JOURNAL OF MEDICINAL CHEMISTRY, 1974, 17 (06) : 624 - 630
[3] POLAROGRAPHIC STUDY OF 1-METHYL-5-ORTHO-CHLOROPHENYL-7-ETHYL-1,2-DIHYDRO-3H-THIENO[2,3-E],[1,4]-DIAZEPIN-2-ONE (CLOTIAZEPAM)
ROJAS, RMA
HERNANDEZHERNANDEZ, L
ANALYTICA CHIMICA ACTA, 1986, 186 : 295 - 299
[4] Synthesis of thieno[2,3-e][1,4]diazepine derivatives
Pokhodylo, N. T.
Shiika, O. Ya
Obushak, M. D.
RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2014, 50 (03) : 449 - 451
[5] Synthesis of thieno[2,3-e][1,4]diazepine derivatives
N. T. Pokhodylo
O. Ya. Shiika
M. D. Obushak
Russian Journal of Organic Chemistry, 2014, 50 : 449 - 451
[6] ATTEMPTED SYNTHESIS OF 5-(2,6-DICHLOROPHENYL)-1H-THIENO-[2,3-E][1,4]DIAZEPIN-2(3H)-ONE
BINDER, D
STANETTY, P
JOURNAL OF CHEMICAL RESEARCH-S, 1981, (04): : 102 - 102
[7] 6,7-dimethyl-5-phenyl-1H-thieno[2,3-e]-[1,4]diazepin-2(3H)-one
Scammells, PJ
Tranberg, CE
Tiekink, ERT
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2001, 57 : o344 - o345
[8] SYNTHESIS OF 7-METHOXYCARBONYL-5-PHENYL-1H-THIENO[2,3-E]1,4-DIAZEPIN-2(3H)-ON
HROMATKA, O
BINDER, D
VEIT, W
MONATSHEFTE FUR CHEMIE, 1973, 104 (04): : 973 - 978
[9] SYNTHESIS OF 2,3-DIHYDRO-IMIDAZO[1,2-C]PYRIMIDO[5',4'-4,5]THIEN[2,3-E]PYRIMIDINES AND 2H-3,4-DIHYDRO-PYRIMIDO[1,2-C]PYRIMIDO[5',4'-4,5]THIENO[2,3-E]PYRIMIDINES
WAGNER, G
VIEWEG, H
LEISTNER, S
PHARMAZIE, 1993, 48 (08): : 588 - 591
[10] NITRATION OF 7-CHLOR-5-PHENYL-1H-THIENO[2,3-E]-1,4-DIAZEPIN-2(3H)-ONE
HROMATKA, O
BINDER, D
STANETTY, P
MONATSHEFTE FUR CHEMIE, 1973, 104 (03): : 709 - 714

← 1 2 3 4 5 →