Reactions of C-60 with R(3)SnH: A new synthetic route to C-60(RH)(n) and the property of C-60 to catalyze radical reactions

被引：0
|
作者：
She, YM [1 ]
Tu, YP [1 ]
Guo, XH [1 ]
Liu, ZY [1 ]
Liu, SY [1 ]
机构：
[1] CHINESE ACAD SCI,CHANGCHUN INST APPL CHEM,CHANGCHUN 130022,PEOPLES R CHINA
来源：
CHINESE CHEMICAL LETTERS | 1996年 / 7卷 / 05期
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D O I：
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中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new method for the preparation of polyalkyl and polyarenefullerene derivatives C-60(RH)(n)(R=Bu,n=1-3; R=Ph,n=1-10) by the reaction of C-60 with organotin hydride in toluene is described. Another series of products of stannanes R(a)Sn(b)H(c) (R=Bu, a=3-8, b=1-4, c=0-3 R=Ph, a=3-11, b=1-5, c=0-4) were also obtained, which shows that C-60 can catalyze polymerization of organic-tin. These products were determined by mass and infrared spectrometry. And the possible reaction mechanisms are discussed.
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页码：433 / 436
页数：4
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