Reactions of C-60 with R(3)SnH: A new synthetic route to C-60(RH)(n) and the property of C-60 to catalyze radical reactions

被引：0
|
作者：
She, YM [1 ]
Tu, YP [1 ]
Guo, XH [1 ]
Liu, ZY [1 ]
Liu, SY [1 ]
机构：
[1] CHINESE ACAD SCI,CHANGCHUN INST APPL CHEM,CHANGCHUN 130022,PEOPLES R CHINA
来源：
CHINESE CHEMICAL LETTERS | 1996年 / 7卷 / 05期
关键词：
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new method for the preparation of polyalkyl and polyarenefullerene derivatives C-60(RH)(n)(R=Bu,n=1-3; R=Ph,n=1-10) by the reaction of C-60 with organotin hydride in toluene is described. Another series of products of stannanes R(a)Sn(b)H(c) (R=Bu, a=3-8, b=1-4, c=0-3 R=Ph, a=3-11, b=1-5, c=0-4) were also obtained, which shows that C-60 can catalyze polymerization of organic-tin. These products were determined by mass and infrared spectrometry. And the possible reaction mechanisms are discussed.
引用
收藏
页码：433 / 436
页数：4
相关论文
共 50 条
  • [31] C-60 - BUCKMINSTERFULLERENE
    KROTO, HW
    HEATH, JR
    OBRIEN, SC
    CURL, RF
    SMALLEY, RE
    NATURE, 1985, 318 (6042) : 162 - 163
  • [32] OSMYLATION OF C-60
    HAWKINS, JM
    MEYER, A
    LEWIS, TA
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1992, 203 : 688 - INOR
  • [33] PROBING C-60
    CURL, RF
    SMALLEY, RE
    SCIENCE, 1988, 242 (4881) : 1017 - 1022
  • [34] Solubility of C-60
    Beck, MT
    Mandi, G
    FULLERENE SCIENCE AND TECHNOLOGY, 1997, 5 (02): : 291 - 310
  • [35] PHOTOFRAGMENTATION OF C-60
    HOHMANN, H
    EHLICH, R
    FURRER, S
    KITTELMANN, O
    RINGLING, J
    CAMPBELL, EEB
    ZEITSCHRIFT FUR PHYSIK D-ATOMS MOLECULES AND CLUSTERS, 1995, 33 (02): : 143 - 151
  • [36] Designs on C-60
    Kroto, H
    CHEMISTRY IN BRITAIN, 1996, 32 (09) : 32 - 36
  • [37] WHAT IS C-60
    OSAWA, E
    TETSU TO HAGANE-JOURNAL OF THE IRON AND STEEL INSTITUTE OF JAPAN, 1993, 79 (04): : N257 - N262
  • [38] C-60 polymers
    Rao, AM
    Eklund, PC
    CLUSTER ASSEMBLED MATERIALS, 1996, 232 : 173 - 206
  • [39] C-60 HISTORY
    REES, LVC
    CHEMISTRY IN BRITAIN, 1993, 29 (06) : 526 - 526
  • [40] CHARGE-TRANSFER REACTIONS OF C-60(3+) - BRACKETING THE 3RD IONIZATION-ENERGY OF C-60
    JAVAHERY, G
    WINCEL, H
    PETRIE, S
    BOHME, DK
    CHEMICAL PHYSICS LETTERS, 1993, 204 (5-6) : 467 - 472
12345