Reactions of C-60 with R(3)SnH: A new synthetic route to C-60(RH)(n) and the property of C-60 to catalyze radical reactions

被引：0
|
作者：
She, YM [1 ]
Tu, YP [1 ]
Guo, XH [1 ]
Liu, ZY [1 ]
Liu, SY [1 ]
机构：
[1] CHINESE ACAD SCI,CHANGCHUN INST APPL CHEM,CHANGCHUN 130022,PEOPLES R CHINA
来源：
CHINESE CHEMICAL LETTERS | 1996年 / 7卷 / 05期
关键词：
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new method for the preparation of polyalkyl and polyarenefullerene derivatives C-60(RH)(n)(R=Bu,n=1-3; R=Ph,n=1-10) by the reaction of C-60 with organotin hydride in toluene is described. Another series of products of stannanes R(a)Sn(b)H(c) (R=Bu, a=3-8, b=1-4, c=0-3 R=Ph, a=3-11, b=1-5, c=0-4) were also obtained, which shows that C-60 can catalyze polymerization of organic-tin. These products were determined by mass and infrared spectrometry. And the possible reaction mechanisms are discussed.
引用
收藏
页码：433 / 436
页数：4
相关论文
共 50 条
  • [1] REACTIONS　OF　C60　WITH　R3SnH:　A　NEW　SYNTHETIC　TO　C60(RH)n　AND　THE　PROPERTY　OF　C60　TO　CATALYZE　RADICAL　REACTIONS
    Yi Min SHE
    Ya Ping TU
    Xing Hua GUO
    Zi Yang LIU
    Shu Ying LIU (Changchun Institute of Applied Chemistry Chinese Academy of Sciences
    ChineseChemicalLetters, 1996, (05) : 433 - 436
  • [2] VIBRONIC COUPLING IN C-60 AND C-60(3-)
    FAULHABER, JCR
    KO, DYK
    BRIDDON, PR
    PHYSICAL REVIEW B, 1993, 48 (01): : 661 - 664
  • [3] GAS-PHASE REACTIONS OF THE BUCKMINSTERFULLERENE CATIONS C-60(.+), C-60(2+), AND C-60(.3+) WITH WATER, ALCOHOLS, AND ETHERS
    JAVAHERY, G
    PETRIE, S
    WINCEL, H
    WANG, J
    BOHME, DK
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (14) : 6295 - 6301
  • [4] REACTIONS OF DIAMINES WITH FULLERENE C-60
    KAMPE, KD
    EGGER, N
    LIEBIGS ANNALEN, 1995, (01): : 115 - 124
  • [5] (NH4)(3)C-60: A new C-60 superconductor?
    Ruoff, RS
    JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (21): : 8973 - 8976
  • [6] Photochemical reactions of oligosilanes with C-60
    Kusakawa, T
    Ando, W
    ORGANOMETALLICS, 1997, 16 (19) : 4027 - 4029
  • [7] Reactions and Properties of Fullerene (C-60)
    Lim, Choong-Sun
    Hong, Seong Kyu
    Ko, Weon Bae
    ELASTOMERS AND COMPOSITES, 2010, 45 (02): : 74 - 79
  • [8] A study of the radical reaction of C-60 with n-Bu(3)SnH
    She, YM
    Guo, XH
    Liu, ZY
    Liu, SY
    Fu, FX
    Qian, MX
    CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 1996, 17 (02): : 303 - 305
  • [9] EXPERIMENTAL-STUDY OF REACTIONS OF THE BUCKMINSTERFULLERENE CATIONS C-60(.+), C-60(2+), AND C-60(.3+) WITH AMMONIA AND AMINES IN THE GAS-PHASE
    JAVAHERY, G
    PETRIE, S
    WINCEL, H
    WANG, JR
    BOHME, DK
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (13) : 5716 - 5722
  • [10] C-60 AS A RADICAL SPONGE
    MCEWEN, CN
    MCKAY, RG
    LARSEN, BS
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (11) : 4412 - 4414
12345