Synthesis and spectroscopic characterization of trazodone charge transfer complexes with different types of π-acceptors

被引：7

作者：

El-Habeeb, Abeer A. ^{[1
]}

Refat, Moamen S. ^{[2
,3
]}

机构：

[1] Princess Nora Bint Abdul Rahman Univ, Dept Chem, Fac Sci, Riyadh, Saudi Arabia

[2] Port Said Univ, Dept Chem, Fac Sci, Port Said, Egypt

[3] Taif Univ, Dept Chem, Fac Sci, At Taif 21974, Saudi Arabia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2015年 / 85卷 / 04期

关键词：

trazodone hydrochloride; charge transfer complexes; conductivity; TCNQ; DCQ; PA; OPTICAL BAND-GAP; O-CHLORANIL; DRUG; ACETYLACETONATE; HYDROCHLORIDE; MECHANISM;

D O I：

10.1134/S1070363215040325

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Charge transfer complexes (CTC) of trazodone hydrochloride (TZD) with picric acid (PA), 2,3-dichloro-5,6-dicyano-p-benzoquinone (DDQ), tetracyanoquinodimethane (TCNQ), 2,6-dichloroquinone-4-chloroimide (DCQ), 2,6-dibromoquinone-4-chloroimide (DBQ), and N-bromosuccinimide (NBS) have been synthesized and studied using conductivity, UV-Vis, infrared, Raman and H-1 NMR spectroscopy. The stoichiometries of the complexes were found to be 1: 1. Kinetic thermodynamic parameters (E*, A, Delta S*, Delta H*, and Delta G*) were also calculated using Coats-Redfern and Horowitz-Metzger equations.

引用

页码：951 / 958

页数：8

共 50 条

[41] Synthesis and spectroscopic structural investigations of the charge-transfer complexes formed in the reaction of 2,6-diaminopyridine with π-acceptors TCNE, chloranil, and DDQ
Bazzi, Hassan S.
Mostafa, Adel
AlQaradawi, Siham Y.
Nour, El-Metwally
JOURNAL OF MOLECULAR STRUCTURE, 2007, 842 (1-3) : 1 - 5
[42] CHARGE-TRANSFER COMPLEXES OF PYRENE WITH DINITROBENZENE AND TRINITROBENZENE ACCEPTORS
AYAD, MM
ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS, 1994, 187 : 123 - 133
[43] Charge-transfer complexes of 4-methylpiperidine with σ- and π-acceptors
AlQaradawi, Siham Y.
Mostafa, Adel
Bazzi, Hassan S.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2015, 135 : 498 - 505
[44] Charge-transfer complexes of Oxazolones with Nitrobenzene a-Acceptors
Microchem J, 3 (263):
[45] CHARGE-TRANSFER COMPLEXES BETWEEN POLYENES AND AROMATIC ACCEPTORS
BARBOY, N
FEITELSON, J
PHOTOCHEMISTRY AND PHOTOBIOLOGY, 1978, 28 (03) : 421 - 424
[46] CHARGE-TRANSFER COMPLEXES OF BENZANILIDES WITH PI-ACCEPTORS
MOURAD, AFE
REVUE ROUMAINE DE CHIMIE, 1988, 33 (06) : 617 - 622
[47] CHARGE-TRANSFER COMPLEXES WITH NITRATE ESTERS AS ELECTRON ACCEPTORS
URBANSKI, T
POLUDNIK.W
HETNARSK.B
CANADIAN JOURNAL OF CHEMISTRY, 1972, 50 (20): : 3340 - &
[48] CHARGE-TRANSFER COMPLEXES OF ALKYLTHIOUREAS WITH PI-ACCEPTORS
HAMED, MMA
SALMAN, HMA
ELGYAR, SA
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 1992, 71 (1-4): : 185 - 192
[49] Infrared Spectra of Charge Transfer Complexes of Biocytin With Organic Acceptors
Padhiyar, Ashvin
Patel, A. J.
Oza, A. T.
MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 2012, 552 : 228 - 246
[50] Charge transfer molecular complexes of some pyrazoles with σ- and π-electron acceptors
Hamed, MMA
Abdalla, EM
Bayoumi, SM
SPECTROSCOPY LETTERS, 2003, 36 (04) : 357 - 373

← 1 2 3 4 5 →