Synthesis and spectroscopic characterization of trazodone charge transfer complexes with different types of π-acceptors

被引：7

作者：

El-Habeeb, Abeer A. ^{[1
]}

Refat, Moamen S. ^{[2
,3
]}

机构：

[1] Princess Nora Bint Abdul Rahman Univ, Dept Chem, Fac Sci, Riyadh, Saudi Arabia

[2] Port Said Univ, Dept Chem, Fac Sci, Port Said, Egypt

[3] Taif Univ, Dept Chem, Fac Sci, At Taif 21974, Saudi Arabia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2015年 / 85卷 / 04期

关键词：

trazodone hydrochloride; charge transfer complexes; conductivity; TCNQ; DCQ; PA; OPTICAL BAND-GAP; O-CHLORANIL; DRUG; ACETYLACETONATE; HYDROCHLORIDE; MECHANISM;

D O I：

10.1134/S1070363215040325

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Charge transfer complexes (CTC) of trazodone hydrochloride (TZD) with picric acid (PA), 2,3-dichloro-5,6-dicyano-p-benzoquinone (DDQ), tetracyanoquinodimethane (TCNQ), 2,6-dichloroquinone-4-chloroimide (DCQ), 2,6-dibromoquinone-4-chloroimide (DBQ), and N-bromosuccinimide (NBS) have been synthesized and studied using conductivity, UV-Vis, infrared, Raman and H-1 NMR spectroscopy. The stoichiometries of the complexes were found to be 1: 1. Kinetic thermodynamic parameters (E*, A, Delta S*, Delta H*, and Delta G*) were also calculated using Coats-Redfern and Horowitz-Metzger equations.

引用

页码：951 / 958

页数：8

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