Synthesis and spectroscopic characterization of trazodone charge transfer complexes with different types of π-acceptors

被引：7
|
作者：
El-Habeeb, Abeer A. [1 ]
Refat, Moamen S. [2 ,3 ]
机构：
[1] Princess Nora Bint Abdul Rahman Univ, Dept Chem, Fac Sci, Riyadh, Saudi Arabia
[2] Port Said Univ, Dept Chem, Fac Sci, Port Said, Egypt
[3] Taif Univ, Dept Chem, Fac Sci, At Taif 21974, Saudi Arabia
来源：
RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2015年 / 85卷 / 04期
关键词：
trazodone hydrochloride; charge transfer complexes; conductivity; TCNQ; DCQ; PA; OPTICAL BAND-GAP; O-CHLORANIL; DRUG; ACETYLACETONATE; HYDROCHLORIDE; MECHANISM;
D O I：
10.1134/S1070363215040325
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Charge transfer complexes (CTC) of trazodone hydrochloride (TZD) with picric acid (PA), 2,3-dichloro-5,6-dicyano-p-benzoquinone (DDQ), tetracyanoquinodimethane (TCNQ), 2,6-dichloroquinone-4-chloroimide (DCQ), 2,6-dibromoquinone-4-chloroimide (DBQ), and N-bromosuccinimide (NBS) have been synthesized and studied using conductivity, UV-Vis, infrared, Raman and H-1 NMR spectroscopy. The stoichiometries of the complexes were found to be 1: 1. Kinetic thermodynamic parameters (E*, A, Delta S*, Delta H*, and Delta G*) were also calculated using Coats-Redfern and Horowitz-Metzger equations.
引用
收藏
页码：951 / 958
页数：8
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