Solvent effect on the free-radical copolymerization of 2-hydroxyethyl methacrylate with t-butyl acrylate

被引：26

作者：

Fernández-Monreal, C

Martínez, G

Sánchez-Chaves, M

Madruga, EL

机构：

[1] Univ Complutense Madrid, Dept Quim Organ 1, E-28040 Madrid, Spain

[2] CSIC, Inst Ciencia & Tecnol Polimeros, E-28006 Madrid, Spain

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 2001年 / 39卷 / 12期

关键词：

2-hydroxyethyl methacrylate; t-butyl acrylate; radical copolymerization; reactivity ratios; solvent effects; bootstrap effect; hydrogen bonding;

D O I：

10.1002/pola.1180

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The free-radical copolymerization of 2-hydroxyethyl methacrylate with t-butyl acrylate was carried out at 50 degreesC in bulk and in 3 mol.L-1 1,4-dioxane and N,N ' -dimethylformamide solutions. Differences between the apparent reactivity ratios determined in this work indicated a noticeable solvent effect. This is explained with a qualitative bootstrap effect. (C) 2001 John Wiley & Sons, Inc.

引用

页码：2043 / 2048

页数：6

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