High-pressure free-radical copolymerization of ethene and butyl acrylate

被引：16

作者：

Buback, M

Busch, M

Lovis, K

Mahling, FO

机构：

[1] Inst. für Physikalische Chemie, Universität Göttingen, D-37077 Göttingen

来源：

MACROMOLECULAR CHEMISTRY AND PHYSICS | 1996年 / 197卷 / 01期

关键词：

D O I：

10.1002/macp.1996.021970123

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The free-radical copolymerization of ethene and butyl acrylate was studied between 130 and 225 degrees C at pressures from 1500 to 2500 bar. The reactions which were induced either thermally or laser-photochemically were run in two types of continuously operated devices. Reactivity ratio data referring to ethene-rich monomer mixtures are presented. These data allow to estimate the copolymer composition in ethene/butyl acrylate copolymerizations carried out in a wide range of temperatures and pressures.

引用

页码：303 / 313

页数：11

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