Bimetallic Zn and Hf on Silica Catalysts for the Conversion of Ethanol to 1,3-Butadiene

被引：72

作者：

De Baerdemaeker, Trees ^{[1
]}

Feyen, Mathias ^{[2
]}

Mueller, Ulrich ^{[2
]}

Yilmaz, Bilge ^{[3
]}

Xiao, Feng-Shou ^{[4
]}

Zhang, Weiping ^{[5
]}

Yokoi, Toshiyuki ^{[6
]}

Bao, Xinhe ^{[7
]}

Gies, Hermann ^{[8
]}

De Vos, Dirk E. ^{[1
]}

机构：

[1] Katholieke Univ Leuven, Ctr Surface Chem & Catalysis, B-3001 Leuven, Belgium

[2] BASF SE, Proc Res & Chem Engn, D-67056 Ludwigshafen, Germany

[3] BASF Corp, Proc Catalysts & Technol, Iselin, NJ 08830 USA

[4] Zhejiang Univ, Hangzhou 310028, Zhejiang, Peoples R China

[5] Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116024, Peoples R China

[6] Tokyo Inst Technol, Chem Resources Lab, Yokohama, Kanagawa 2268503, Japan

[7] Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China

[8] Ruhr Univ Bochum, Inst Geol Mineral & Geophys, D-44780 Bochum, Germany

来源：

ACS CATALYSIS | 2015年 / 5卷 / 06期

关键词：

1,3-butadiene; ethanol; zinc silicate; hemimorphite; heterogeneous catalysis; silica impregnation; MAGNESIUM-OXIDE; METAL-OXIDES; BUTADIENE; HYDROXYAPATITE; TRANSFORMATION; SELECTIVITY; BASICITY; ACETONE; LEBEDEV;

D O I：

10.1021/acscatal.5b00376

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Silica-supported catalysts for the conversion of ethanol to 1,3-butadiene were investigated. The combination of Hf(IV) and Zn(II) resulted in a stable, active, and selective catalyst in which the Zn(II) effectively suppressed the dehydration activity of Hf(IV); the catalyst preparation method plays a crucial role. Using the crystalline Zn-silicate hemimorphite as an alternative Zn(II) source proved to be even more successful in suppressing ethanol dehydration.

引用

页码：3393 / 3397

页数：5

共 50 条

[41] From Sugars to Wheels: The Conversion of Ethanol to 1,3-Butadiene over Metal-Promoted Magnesia-Silicate Catalysts
Shylesh, Sankaranarayanapillai
Gokhale, Amit A.
Scown, Corinne D.
Kim, Daeyoup
Ho, Christopher R.
Bell, Alexis T.
CHEMSUSCHEM, 2016, 9 (12) : 1462 - 1472
[42] Effect of Preparation Method and CuO Promotion in the Conversion of Ethanol into 1,3-Butadiene over SiO2-MgO Catalysts
Angelici, Carlo
Velthoen, Marjolein E. Z.
Weckhuysen, Bert M.
Bruijnincx, Pieter C. A.
CHEMSUSCHEM, 2014, 7 (09) : 2505 - 2515
[43] Integrated conversion of 1-butanol to 1,3-butadiene
Kruger, Jacob S.
Dong, Tao
Beckham, Gregg T.
Biddy, Mary J.
RSC ADVANCES, 2018, 8 (42): : 24068 - 24074
[44] Selection of oxide supports to anchor desirable bimetallic structures for ethanol reforming and 1,3-butadiene hydrogenation
Wang, Tiefeng
Lonergan, William
Chen, Jingguang G.
CHINESE JOURNAL OF CATALYSIS, 2013, 34 (11) : 2009 - 2017
[45] Selection of oxide supports to anchor desirable bimetallic structures for ethanol reforming and 1,3-butadiene hydrogenation
Wang, Tiefeng
Lonergan, William
Chen, Jingguang G.
Chinese Journal of Catalysis, 2013, 34 (11): : 2009 - 2017
[46] Conversion of ethanol to 1,3-butadiene over Na doped ZnxZryOz mixed metal oxides
Baylon, Rebecca A. L.
Sun, Junming
Wang, Yong
CATALYSIS TODAY, 2016, 259 : 446 - 452
[47] 1,3-Butadiene
Luttrell, William E.
Sizemore, Caroline E.
JOURNAL OF CHEMICAL HEALTH & SAFETY, 2013, 20 (03): : 54 - 56
[48] A DFT study on Zr-SBA-15 catalyzed conversion of ethanol to 1,3-butadiene
Dong, Xiuqin
Lu, Jia
Yu, Yingzhe
Zhang, Minhua
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2018, 20 (18) : 12970 - 12978
[49] γ-alumina supported Cu-Ni bimetallic catalysts:: Characterization and selective hydrogenation of 1,3-butadiene
Kang, M
Song, MW
Kim, TW
Kim, KL
CANADIAN JOURNAL OF CHEMICAL ENGINEERING, 2002, 80 (01): : 63 - 70
[50] Novel Methylaluminoxane-Activated Neodymium Isopropoxide Catalysts for 1,3-Butadiene Polymerization and 1,3-Butadiene/Isoprene Copolymerization
Hu, Yanming
Dong, Weimin
Masuda, Toshio
MACROMOLECULAR CHEMISTRY AND PHYSICS, 2013, 214 (19) : 2172 - 2180

← 1 2 3 4 5 →