Rhodium-catalyzed arylative cyclization of alkynones induced by addition of arylboronic acids

被引：38

作者：

Miura, Tomoya ^{[1
]}

Shimada, Masahiko ^{[1
]}

Murakami, Masahiro ^{[1
]}

机构：

[1] Kyoto Univ, Dept Synthet Chem & Biol Chem, Kyoto 6158510, Japan

来源：

TETRAHEDRON | 2007年 / 63卷 / 27期

基金：

日本学术振兴会;

关键词：

D O I：

10.1016/j.tet.2007.03.025

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Alkynones react with arylboronic acids in the presence of a rhodium(I) catalyst to afford four- and five-membered-ring cyclic alcohols equipped with a tetrasubstituted exocyclic olefin. The cyclic allylic alcohol skeleton is constructed by the carbon-carbon bond formation between the carbonyl group and an alkenylrhodium(I) intermediate formed by the regioselective addition of an arylrhodium(I) species across the carbon-carbon triple bond. (c) 2007 Elsevier Ltd. All rights reserved.

引用

页码：6131 / 6140

页数：10

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