trans-Tetrachlorobis(triphenylphosphine-P)-rhenium(IV)-mer-trans-trichlorooxobis(triphenylphosphine-P)rhenium(V) (0.86/0.14)

被引：5

作者：

Luo, HY

Orvig, C

Rettig, SJ

机构：

[1] Department of Chemistry, University of British Columbia, 2036 Main Mall, Vancouver

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1996年 / 52卷

关键词：

D O I：

10.1107/S0108270196001710

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

trans-Tetrachlorobis (triphenylphosphine)rhenium(rv), (1), is isomorphous with the triclinic polymorph of mer-trans-trichlorooxobis (triphenylphosphine)rhenium(v), (2) [Lebuis & Beauchamp (1993). Cart. J. Chem. 71, 441-449]. The sample of (1) has been partially oxidized (14-25%) to (2) by aerial oxidation, resulting in the title compound, [ReCl4(C18H15P)(2)](0.86)-[ReCl3O(C18H15P)(2)](0.14). In the crystal lattice, the oxo ligand is located primarily at one of six possible sites. The molecules have tuans-octahedral coordination geometry, with Re-P distances in the range 2.564(1)-2.580 (1) Angstrom, having a mean value of 2.571(7) Angstrom, and Re-Cl distances in the range 2.291(3)-2.339 (1)Angstrom.

引用

页码：1377 / 1380

页数：4

共 44 条

[41] Multifaceted Reactions of P(CH2OH)3 with Rhenium(V) Precursors. Synthesis, Characterization, and X-ray Structural Studies of trans,trans,trans-[ReO2{P(CH2OH)3}$ -2$/-( py)2]Cl, trans,cis,cis[ReO2{P(CH2OH)3}2(py)$ -2$/]Cl, and Novel Alkoxide [Re(O)(ae-O)- (P{CH2OH}3)(ae-eta2-P{CH2O H}2 CH2O)]4
Inorg Chem, 2 (334):
[42] Synthesis and structural characterisation of the oxo-rhenium(V) complexes with spirophosphorane derived bidentate ligand (P ∼ O-).: Crystal structure of trans-ReOCl2[OCMe2CMe2OP(OCMe2CMe2O)](PPh3)
Glowiak, T
Rybak, WK
Skarzynska, A
POLYHEDRON, 2000, 19 (28) : 2667 - 2672
[43] SYNTHESIS AND CHARACTERIZATION OF 2 NEW MOLYBDENUM(0) SIGMA-ARYL COMPLEXES OF THE TYPE [N(PPH(3))(2)][MO(C6F5)L(CO)(2)(P(OME)(3))(2)] - X-RAY CRYSTAL-STRUCTURE OF BIS(TRIPHENYLPHOSPHINE)IMINIUM PENTAFLUOROPHENYL(MER-TRICARBONYL) TRANS-BIS(TRIMETHYLPHOSPHITE)MOLYBDATE(0)
MULLICA, DF
GIPSON, SL
SU, M
SAPPENFIELD, EL
POLYHEDRON, 1995, 14 (15-16) : 2215 - 2220
[44] Crystal structure of trans-((2-aminophenolato-κO)-(2-hydroxyphenylimido-κ2N,O)-bromido-bis(triphenylphosphane)-rhenium(V)) bromide - acetonitrile - water (1:2:1), C52H49Br2N4O3P2Re
Mukiza, Janvier
Gerber, Thomas I. A.
Hosten, Eric C.
Betz, Richard
ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2015, 230 (02): : 165 - 167

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