trans-Tetrachlorobis(triphenylphosphine-P)-rhenium(IV)-mer-trans-trichlorooxobis(triphenylphosphine-P)rhenium(V) (0.86/0.14)

被引：5

作者：

Luo, HY

Orvig, C

Rettig, SJ

机构：

[1] Department of Chemistry, University of British Columbia, 2036 Main Mall, Vancouver

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1996年 / 52卷

关键词：

D O I：

10.1107/S0108270196001710

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

trans-Tetrachlorobis (triphenylphosphine)rhenium(rv), (1), is isomorphous with the triclinic polymorph of mer-trans-trichlorooxobis (triphenylphosphine)rhenium(v), (2) [Lebuis & Beauchamp (1993). Cart. J. Chem. 71, 441-449]. The sample of (1) has been partially oxidized (14-25%) to (2) by aerial oxidation, resulting in the title compound, [ReCl4(C18H15P)(2)](0.86)-[ReCl3O(C18H15P)(2)](0.14). In the crystal lattice, the oxo ligand is located primarily at one of six possible sites. The molecules have tuans-octahedral coordination geometry, with Re-P distances in the range 2.564(1)-2.580 (1) Angstrom, having a mean value of 2.571(7) Angstrom, and Re-Cl distances in the range 2.291(3)-2.339 (1)Angstrom.

引用

页码：1377 / 1380

页数：4

共 44 条

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Johannsen, B
POLYHEDRON, 1998, 17 (21) : 3711 - 3720
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Gerber, TIA
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DuPreez, JGH
Bandoli, G
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1997, 53 : 217 - 219
[23] trans-[Bis-2,6-(2-benzimidazolyl-kappa N-2)-pyridine-kappa N]nitrobis(triphenylphosphine-P)ruthenium(II) perchlorate ethanol solvate
Lim, JW
Yeo, HJ
Jeong, JH
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1997, 53 : 1405 - 1407
[24] trans-(4-Amino-2,2,6,6-tetramethyl-piperidine-N4)bis(pentane-2,4-dionato-O,O′)(triphenylphosphine-P)cobalt(III) hexafluorophosphate dichloromethane solvate
Suzuki, T
Ogita, M
Kaizaki, S
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 2000, 56 : 532 - 533
[25] SYNTHESIS, CHARACTERIZATION AND X-RAY CRYSTAL-STRUCTURE OF CIS-TETRAKIS(ISOTHIOCYANATO)(TRIPHENYLPHOSPHINE)(TRIPHENYLPHOSPHINE OXIDE)RHENIUM(IV), [RE(NCS)4(PH3P)(PH3PO)]
HUBENER, R
ABRAM, U
INORGANICA CHIMICA ACTA, 1993, 211 (01) : 121 - 123
[26] CRYSTAL-STRUCTURE OF MER-HYDRIDO-BIS-TRIPHENYLPHOSPHINE-TRICARBONYL-RHENIUM, (H)(P(C6H5)3)2(CO)3RE
FLORKE, U
HAUPT, HJ
ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1992, 202 (3-4): : 317 - 319
[27] THE STRUCTURE OF TRANS-DIBROMOOXO(N-PHENYLSALICYLIDENEAMINATO)(TRIPHENYLPHOSPHINE)RHENIUM(V), FORM-II (TRICLINIC), [REBR2(C13H10NO)O(P(C6H5)3)]
SACERDOTI, M
BERTOLASI, V
GILLI, G
DUATTI, A
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1984, 40 (JUN) : 968 - 970
[28] CRYSTAL-STRUCTURE OF MER-TRICARBONYL-CHLORO-BIS-(TRIPHENYLPHOSPHINE)RHENIUM, (CO)3CL(P(C6H5)3)2RE
FLORKE, U
HAUPT, HJ
ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1993, 204 : 316 - 318
[29] mer,trans-[bis(2-diphenylphosphino-ethyl)(n-propyl)amine-N,P,P']dichloro-(triphenylphosphine)ruthenium(II) 0.5-dichloromethane solvate
Bianchini, C
Masi, D
Peruzzini, M
Romerosa, A
Zanobini, F
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1995, 51 : 2514 - 2517
[30] (2-Hydroxyphenylimido-κN)(methanolato-κO)[2-(2-oxidobenzyl-ideneamino)phenolato-κ2O,N,O′](triphenylphosphine-κP)rhenium(V)
Holland, Jason P.
Barnard, Peter J.
Dilworth, Jonathan R.
Watkin, David J.
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : M773 - U385

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