Novel tricarbonyl rhenium complexes of 5,8-quinolinedione derivatives e Synthesis, spectroscopic characterisation, X-ray structure and DFT calculations

被引：7

作者：

Machura, B. ^{[1
]}

Switlicka, A. ^{[1
]}

Wolff, M. ^{[1
]}

Tabak, D. ^{[2
]}

Musiol, R. ^{[2
]}

Polanski, J. ^{[2
]}

Kruszynski, R. ^{[3
]}

机构：

[1] Silesian Univ, Inst Chem, Dept Crystallog, PL-40006 Katowice, Poland

[2] Silesian Univ, Inst Chem, Dept Organ Chem, PL-40006 Katowice, Poland

[3] Tech Univ Lodz, Inst Gen & Ecol Chem, Dept Xray Crystallog & Crystal Chem, PL-90924 Lodz, Poland

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2011年 / 696卷 / 03期

关键词：

Rhenium(I) carbonyl complexes; 5,8-Quinolinedione derivatives; X-ray structure; UV-vis spectra; DFT calculations; CARBONYL-DIIMINE COMPLEXES; RADIOPHARMACEUTICALS; POTENTIALS; ELECTRON; LIGANDS; DENSITY; ANALOGS;

D O I：

10.1016/j.jorganchem.2010.09.058

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The molecular structure of 7-acetamido-2-methyl-quinoline-5,8-dione has been determined and the reactivity of 7-acetamido-2-methyl-quinoline-5,8-dione (1) and 6-acetamido-2-methyl-quinoline-5,8-dione (2) towards Re(CO)(5)Cl has been examined. Two novel tricarbonyl rhenium complexes, fac-[Re(CO)(3)(7-acetamido-2-methyl-quinoline-5,8-dione) Cl]center dot CHCl(3) (3 center dot CHCl(3)) and fac-[Re(CO)(3)(6-acetamido-2-methyl-quinoline-5,8-dione) Cl](2)center dot CHCl(3)(4 center dot CHCl(3)), have been synthesized and characterized spectroscopically and structurally. The electronic spectrum of 3 was investigated at the TDDFT level employing B3LYP functional in combination with LANL2DZ. (C) 2010 Elsevier B.V. All rights reserved.

引用

页码：731 / 738

页数：8

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