Novel Re(I) tricarbonyl complexes of chelating ligands with aromatic N-heterocycle ring and aliphatic amine donor - Synthesis, spectroscopic characterization, X-ray structure and DFT calculations

被引：16

作者：

Machura, B. ^{[1
]}

Wolff, M. ^{[1
]}

Gryca, I. ^{[1
]}

Palion, A. ^{[1
]}

Michalik, K. ^{[2
]}

机构：

[1] Univ Silesia, Inst Chem, Dept Crystallog, PL-40006 Katowice, Poland

[2] Univ Silesia, A Chelkowski Inst Phys, Dept Med Phys, PL-40007 Katowice, Poland

来源：

POLYHEDRON | 2011年 / 30卷 / 13期

关键词：

Rhenium(I) carbonyl complexes; X-ray structure; UV-Vis spectra; DFT calculations; EXCITED-STATE; RHENIUM; TECHNETIUM; CHEMISTRY;

D O I：

10.1016/j.poly.2011.06.001

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Three novel tricarbonyl rhenium(I) complexes of chelating ligands with aromatic N-heterocycle ring and aliphatic amine donor (2-aminomethylpyridine (ampy), 2-(2-aminophenyl)-1H-benzimidazole (apbi) and 2-(2-aminophenyl)benzothiazole (apbt)) have been synthesized and characterized. The compounds [Re(CO)(3)(ampy)Cl] (1), [Re(CO)(3)(apbi)Cl] (2) and [Re(CO)(3)(apbt)Cl] (3) have been identified by IR, UV-Vis spectroscopy and X-ray analysis. The experimental studies on the complexes 1, 2 and 3 have been accompanied computationally by the density functional theory (OFT) calculations. (C) 2011 Elsevier Ltd. All rights reserved.

引用

页码：2275 / 2285

页数：11

共 50 条

[1] Novel imino rhenium(I) tricarbonyl complexes of salicylidene-derived ligands: Synthesis, X-ray crystallographic studies, spectroscopic characterization and DFT calculations
Brink, A.
Visser, H. G.
Roodt, A.
POLYHEDRON, 2013, 52 : 416 - 423
[2] Tricarbonyl rhenium(I) complex of benzothiazole - Synthesis, spectroscopic characterization, X-ray crystal structure and DFT calculations
Machura, B.
Wolff, M.
Benoist, E.
Coulais, Y.
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2013, 724 : 82 - 87
[3] A novel tricarbonyl rhenium complex of 2-benzoylpyridine - Synthesis, spectroscopic characterization, X-ray structure and DFT calculations
Machura, B.
Kruszynski, R.
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2007, 692 (19) : 4161 - 4167
[4] Palladium(II) complexes of terdentate azo ligands with an O,N,S donor set: Synthesis, spectroscopic characterization, X-ray structure and TD-DFT calculations
Acharya, Suvra
Kejriwal, Ambica
Biswas, Achintesh Narayan
Das, Purak
Neogi, Debatra Narayan
Bandyopadhyay, Pinaki
POLYHEDRON, 2012, 38 (01) : 50 - 57
[5] Novel thiocyanate complexes of cadmium(II) - Synthesis, spectroscopic characterization, X-ray studies and DFT calculations
Machura, B.
Nawrot, I.
Michalik, K.
POLYHEDRON, 2011, 30 (15) : 2619 - 2626
[6] Novel tricarbonyl rhenium complexes of 5,8-quinolinedione derivatives e Synthesis, spectroscopic characterisation, X-ray structure and DFT calculations
Machura, B.
Switlicka, A.
Wolff, M.
Tabak, D.
Musiol, R.
Polanski, J.
Kruszynski, R.
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2011, 696 (03) : 731 - 738
[7] Novel rhenium(V) complexes of 8-hydroxyquinoline derivatives - Synthesis, spectroscopic characterization, X-ray structure and DFT calculations
Machura, B.
Wolff, M.
Kowalczyk, W.
Musiol, R.
POLYHEDRON, 2012, 33 (01) : 388 - 395
[8] Synthesis, spectroscopic characterization, X-ray structure and DFT calculations of novel mononuclear Re(V) complex with imidazole-derived ligand
Machura, B.
Wolff, M.
Palion, J.
Kruszynski, R.
INORGANIC CHEMISTRY COMMUNICATIONS, 2011, 14 (09) : 1358 - 1361
[9] Synthesis, spectroscopic characterization, X-ray structure, and DFT calculations of [Cu(tppz)(SCN)2]
Machura, B.
Switlicka, A.
Palion, J.
Kruszynski, R.
STRUCTURAL CHEMISTRY, 2013, 24 (01) : 89 - 96
[10] Synthesis, spectroscopic characterization, X-ray structure, and DFT calculations of [Cu(tppz)(SCN)2]
B. Machura
A. Świtlicka
J. Palion
R. Kruszynski
Structural Chemistry, 2013, 24 : 89 - 96

← 1 2 3 4 5 →