Novel tricarbonyl rhenium complexes of 5,8-quinolinedione derivatives e Synthesis, spectroscopic characterisation, X-ray structure and DFT calculations

被引：7
|
作者：
Machura, B. [1 ]
Switlicka, A. [1 ]
Wolff, M. [1 ]
Tabak, D. [2 ]
Musiol, R. [2 ]
Polanski, J. [2 ]
Kruszynski, R. [3 ]
机构：
[1] Silesian Univ, Inst Chem, Dept Crystallog, PL-40006 Katowice, Poland
[2] Silesian Univ, Inst Chem, Dept Organ Chem, PL-40006 Katowice, Poland
[3] Tech Univ Lodz, Inst Gen & Ecol Chem, Dept Xray Crystallog & Crystal Chem, PL-90924 Lodz, Poland
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2011年 / 696卷 / 03期
关键词：
Rhenium(I) carbonyl complexes; 5,8-Quinolinedione derivatives; X-ray structure; UV-vis spectra; DFT calculations; CARBONYL-DIIMINE COMPLEXES; RADIOPHARMACEUTICALS; POTENTIALS; ELECTRON; LIGANDS; DENSITY; ANALOGS;
D O I：
10.1016/j.jorganchem.2010.09.058
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The molecular structure of 7-acetamido-2-methyl-quinoline-5,8-dione has been determined and the reactivity of 7-acetamido-2-methyl-quinoline-5,8-dione (1) and 6-acetamido-2-methyl-quinoline-5,8-dione (2) towards Re(CO)(5)Cl has been examined. Two novel tricarbonyl rhenium complexes, fac-[Re(CO)(3)(7-acetamido-2-methyl-quinoline-5,8-dione) Cl]center dot CHCl(3) (3 center dot CHCl(3)) and fac-[Re(CO)(3)(6-acetamido-2-methyl-quinoline-5,8-dione) Cl](2)center dot CHCl(3)(4 center dot CHCl(3)), have been synthesized and characterized spectroscopically and structurally. The electronic spectrum of 3 was investigated at the TDDFT level employing B3LYP functional in combination with LANL2DZ. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码：731 / 738
页数：8
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