ELECTROCHEMICAL CHARACTERISTICS OF Ni/Gd-DOPED CERIA AND Ni/Sm-DOPED CERIA ANODES FOR SOFC USING DRY METHANE FUEL

被引:0
|
作者
Levy, Caroline [1 ]
Hasegawa, Shinichi [1 ]
Nakamura, Shiko [1 ]
Ihara, Manabu [1 ]
Yamahara, Keiji [2 ]
机构
[1] Tokyo Inst Technol, Res Ctr Carbon Recycling & Energy, Meguro Ku, 2-12-1 Ookayama, Tokyo 1528852, Japan
[2] Mitsubishi Chem Corp, Tokyo 108, Japan
来源
ADVANCES IN SOLID OXIDE FUEL CELLS II | 2007年 / 27卷 / 04期
关键词
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中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
This research was carried out on the study of SOFCs working with hydrogen (H-2) and dry methane (CH4) fuels with a cermet anode of nickel (Ni)/fluorite type material as Gadolinium doped ceria (GDC) and Samarium doped ceria (SDC) to compare with Ni/Yttria-stabilized zirconia (YSZ) anode at 900 degrees C. We observed that the performances with Ni/GDC and Ni/SDC anodes obtained with H-2 and dry CH4 were better than those obtained with Ni/YSZ anode. After degradation tests, the SOFC with Ni/GDC anode conserved high performances, while Ni/YSZ anode was degraded. The degradation of the SOFCs in dry CH4 fuel was accelerated by the interruption of the current. Thus, Nil doped ceria anodes had similar behaviour and could be suitable candidates as anodes in SOFC with dry CH4 fuel.
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页码:175 / +
页数:2
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