NdMo7.7O14 containing Mo6, Mo7 and Mo8 clusters

被引：1
|
作者：
Barrier, N [1 ]
Gougeon, P [1 ]
机构：
[1] Univ Rennes 1, CNRS, URA 6511, Chim Solide & Inorgan Mol Lab, F-35042 Rennes, France
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2001年 / 57卷
关键词：
D O I：
10.1107/S1600536801007103
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
Neodymium molybdenum oxide, NdMo7.7O14, crystallizes in the orthorhombic space group Aba2. Its crystal structure derives from the NdMo8O14 type which contains bicapped octahedral Mo-8 clusters. Because of the non-stoichiometry on the capping Mo sites and the absence of satellite reflections, Mo-6, Mo-7 and Mo-8 clusters are expected to co-exist randomly.
引用
收藏
页码：i46 / I48
页数：3
相关论文
共 50 条
  • [21] The molybdenum diphosphate Mo1.3O(P2O7), containing Mo2 and Mo3 clusters
    Lisnyak, VV
    Stus, NV
    Popovich, P
    Stratiychuk, DA
    Filinchuk, Y
    Davydov, VM
    JOURNAL OF ALLOYS AND COMPOUNDS, 2003, 360 (1-2) : 81 - 84
  • [22] NEW SUPRACONDUCTING COMPOUND CONTAINING MO-6 CLUSTERS - CS0.6MO6S7
    GOUGEON, P
    POTEL, M
    PADIOU, J
    SERGENT, M
    COMPTES RENDUS DE L ACADEMIE DES SCIENCES SERIE II, 1983, 297 (04): : 339 - 342
  • [23] Syntheses and structural trends of the InxMo15S19 (0 ≤ x ≤ 3.7) compounds containing Mo6 and Mo9 clusters
    Salloum, D
    Gautier, R
    Gougeon, P
    Potel, M
    JOURNAL OF SOLID STATE CHEMISTRY, 2004, 177 (4-5) : 1672 - 1680
  • [24] ONE-DIMENSIONAL CONDENSATION OF MO6 OCTAHEDRAL CLUSTERS - A NEW CLUSTER, MO12, AND A NEW BUILDING BLOCK, MO12S14, IN M2MO9S11
    CHEVREL, R
    POTEL, M
    SERGENT, M
    DECROUX, M
    FISCHER, O
    JOURNAL OF SOLID STATE CHEMISTRY, 1980, 34 (02) : 247 - 251
  • [25] Electronic structure, electrical and magnetic properties of RMo8O14 compounds (R = La, Ce, Pr, Nd, Sm) containing bicapped Mo8 clusters
    Gautier, R
    Andersen, OK
    Gougeon, P
    Halet, JF
    Canadell, E
    Martin, JD
    INORGANIC CHEMISTRY, 2002, 41 (18) : 4689 - 4699
  • [26] SINGLE-CRYSTAL INVESTIGATION OF NI0.8MO6TE8 WITH TRICLINICALLY DISTORTED MO6 OCTAHEDRONS
    HONLE, W
    YVON, K
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1983, 162 (1-4): : 103 - 104
  • [27] CONDENSATION OF PATTERNS (MO6L14) IN THE CHEMISTRY OF MO-6 OCTAHEDRAL CLUSTERS
    PERRIN, C
    SERGENT, M
    JOURNAL OF THE LESS-COMMON METALS, 1986, 123 : 117 - 133
  • [28] RAMAN STUDIES ON ROCK-FORMING MINERALS .2. MINERALS CONTAINING MO3, MO4, AND MO6 GROUPS
    GRIFFITH, WP
    JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1970, (02): : 286 - +
  • [29] Ba4Mo12S18:: A superconductor containing the dimeric unit (Mo6)2S24, the missing link between the Mo6S14 and Mo9S17 units
    Salloum, D
    Gautier, R
    Potel, M
    Gougeon, P
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (09) : 1363 - 1365
  • [30] IN11MO40O62 - A MOLYBDATE WITH UNITS OF 4 AND 5 CONDENSED MO6 OCTAHEDRA AND LINEAR IN-5(7+) AND IN-6(8+) IONS
    MATTAUSCH, H
    SIMON, A
    PETERS, EM
    INORGANIC CHEMISTRY, 1986, 25 (19) : 3428 - 3433
12345