Simple and efficient AuI-based catalyst for hydroamination of alkynes

被引：11
|
作者：
Anokhin, Maksim V. [1 ]
Murashkina, Anna V. [1 ]
Averin, Alexei D. [1 ]
Beletskaya, Irina P. [1 ]
机构：
[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119991, Russia
来源：
MENDELEEV COMMUNICATIONS | 2014年 / 24卷 / 06期
基金：
俄罗斯科学基金会;
关键词：
INTERMOLECULAR HYDROAMINATION; REDUCTIVE AMINATION; ASYMMETRIC HYDROGENATION; HIGHLY EFFICIENT; GOLD(I) COMPLEX; ALKENES; ALLENES;
D O I：
10.1016/j.mencom.2014.11.004
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Hydroamination of terminal alkynes with anilines in the presence of (C6F5)(3)PAuNTf2 catalyst affords 2-aryliminoalkanes whose reduction in situ with sodium borohydride gives the corresponding secondary amines in high yields.
引用
收藏
页码：332 / 333
页数：2
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