Simple and efficient AuI-based catalyst for hydroamination of alkynes

被引:11
|
作者
Anokhin, Maksim V. [1 ]
Murashkina, Anna V. [1 ]
Averin, Alexei D. [1 ]
Beletskaya, Irina P. [1 ]
机构
[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119991, Russia
基金
俄罗斯科学基金会;
关键词
INTERMOLECULAR HYDROAMINATION; REDUCTIVE AMINATION; ASYMMETRIC HYDROGENATION; HIGHLY EFFICIENT; GOLD(I) COMPLEX; ALKENES; ALLENES;
D O I
10.1016/j.mencom.2014.11.004
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Hydroamination of terminal alkynes with anilines in the presence of (C6F5)(3)PAuNTf2 catalyst affords 2-aryliminoalkanes whose reduction in situ with sodium borohydride gives the corresponding secondary amines in high yields.
引用
收藏
页码:332 / 333
页数:2
相关论文
共 50 条
  • [11] Iridium(II) Cp* Complexes for the Efficient Hydroamination of Internal Alkynes
    Gray, Katherine
    Page, Michael J.
    Wagler, Joerg
    Messerle, Barbara A.
    ORGANOMETALLICS, 2012, 31 (17) : 6270 - 6277
  • [12] Au(I)-catalyzed highly efficient intermolecular hydroamination of alkynes
    Mizushima, E
    Hayashi, T
    Tanaka, M
    ORGANIC LETTERS, 2003, 5 (18) : 3349 - 3352
  • [13] Ruthenium diphosphine complexes as an efficient hydroamination catalyst
    Jahromi, Bahareh Tamaddoni
    Kharat, Ali Nemati
    Amini, Mostafa M.
    Khavasi, Hamidreza
    APPLIED PETROCHEMICAL RESEARCH, 2015, 5 (02): : 105 - 112
  • [14] Multifunctional AuI-based AIEgens: Manipulating Molecular Structures and Boosting Specific Cancer Cell Imaging and Theranostics
    Zhang Jing
    Zou Hang
    Lei Jinping
    He Benzhao
    He Xuewen
    Sung, Herman H. Y.
    Kwok, Ryan T. K.
    Lam, Jacky W. Y.
    Zheng Lei
    Tang Ben Zhong
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2020, 59 (18) : 7097 - 7105
  • [15] An efficient reusable silver-exchanged tungstophosphoric acid heterogeneous catalyst for solvent-free intermolecular hydroamination of alkynes
    Lingaiah, N.
    Babu, N. Seshu
    Reddy, K. Mohan
    Prasad, P. S. Sai
    Suryanarayana, I.
    CHEMICAL COMMUNICATIONS, 2007, (03) : 278 - 279
  • [16] An Efficient and Green Approach to Synthesizing Enamines by Intermolecular Hydroamination of Activated Alkynes
    Zeng Ruijie
    Sheng Hongting
    Rao Bo
    Feng Yan
    Wang Hao
    Sun Yehua
    Chen Man
    Zhu Manzhou
    CHEMICAL RESEARCH IN CHINESE UNIVERSITIES, 2015, 31 (02) : 212 - 217
  • [17] [Ind2TiMe2]:: A general catalyst for the intermolecular hydroamination of alkynes
    Heutling, A
    Pohlki, F
    Doye, S
    CHEMISTRY-A EUROPEAN JOURNAL, 2004, 10 (12) : 3059 - 3071
  • [18] An efficient and green approach to synthesizing enamines by intermolecular hydroamination of activated alkynes
    Ruijie Zeng
    Hongting Sheng
    Bo Rao
    Yan Feng
    Hao Wang
    Yehua Sun
    Man Chen
    Manzhou Zhu
    Chemical Research in Chinese Universities, 2015, 31 : 212 - 217
  • [19] Double Hydroamination of Terminal Alkynes over Beta Zeolite-Supported CuO Catalyst
    Gajula, Krishna Sai
    Macharla, Arun Kumar
    Amrutham, Vasu
    Yennamaneni, Divya Rohini
    Boosa, Murali
    Madasu, Ramulamma
    Chelukalapally, Anil Kumar
    Nama, Narender
    CHEMCATCHEM, 2023, 15 (20)
  • [20] A highly regioselective Cu-exchanged tungstophosphoric acid catalyst for hydroarylation and hydroamination of alkynes
    Pasha, Nayeem
    Babu, N. Seshu
    Rao, K. T. Venkateswara
    Prasad, P. S. Sai
    Lingaiah, N.
    TETRAHEDRON LETTERS, 2009, 50 (02) : 239 - 242