Chiral heterocyclic ligands.: XI.: Self-assembly and X-ray crystal structures of chiral silver coordination polymers of (S)-(-)-nicotine

被引：17

作者：

Lewis, W ^{[1
]}

Steel, PJ ^{[1
]}

机构：

[1] Univ Canterbury, Dept Chem, Christchurch 8020, New Zealand

来源：

SUPRAMOLECULAR CHEMISTRY | 2005年 / 17卷 / 07期

关键词：

coordination polymer; silver; chiral; nicotine; crystal structure;

D O I：

10.1080/10610270500317086

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Three chiral coordination polymers have been prepared by reaction of (S)-(-)-nicotine with silver(I) salts. X-Ray crystal structure determinations revealed that these all contain polymer chains in which the nicotine molecule acts as a bridging ligand between four-coordinate silver atoms. In one case additional bridging by nitrate anions leads to a three-dimensional network structure.

引用

页码：579 / 584

页数：6

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