Chiral heterocyclic ligands.: XI.: Self-assembly and X-ray crystal structures of chiral silver coordination polymers of (S)-(-)-nicotine

被引：17
|
作者：
Lewis, W [1 ]
Steel, PJ [1 ]
机构：
[1] Univ Canterbury, Dept Chem, Christchurch 8020, New Zealand
来源：
SUPRAMOLECULAR CHEMISTRY | 2005年 / 17卷 / 07期
关键词：
coordination polymer; silver; chiral; nicotine; crystal structure;
D O I：
10.1080/10610270500317086
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Three chiral coordination polymers have been prepared by reaction of (S)-(-)-nicotine with silver(I) salts. X-Ray crystal structure determinations revealed that these all contain polymer chains in which the nicotine molecule acts as a bridging ligand between four-coordinate silver atoms. In one case additional bridging by nitrate anions leads to a three-dimensional network structure.
引用
收藏
页码：579 / 584
页数：6
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