GaN high electron mobility transistor (HEMT) structures have been grown by plasma molecular beam epitaxy on 100 mm diameter < 111 > silicon substrates. Crack-free films with thicknesses of up to 1.7 mu m were deposited without the use of strain-relaxing buffer layers. X-ray measurements indicate high structural uniformity and the Pendellosung oscillations are observed due to the abruptness of the AlGaN/GaN interface. Capacitance-voltage measurements display a sharp pinch-off with a depleted GaN buffer layer and no measurable charge accumulation at the substrate-epi interface. Transmission line measurements on the GaN HEMT buffer and substrate indicate a loss of less than 0.2 dB/mm up to 20 GHz. An average sheet resistance of 443 Omega/sq with a standard deviation of 0.8% and a mobility of 1600 cm(2)/V s were obtained for an Al0.25Ga0.75N/GaN HEMT. Transistors were fabricated with a current density of 1.2 A/mm and a transconductance of 290 mS/mm which is quite comparable to GaN HEMTs on SiC. (C) 2011 American Vacuum Society. [DOI: 10.1116/1.3549889]