Mapping chemically heterogeneous polymer system using selective chemical reaction and tapping mode atomic force microscopy

被引：0

作者：

Raghavan, D ^{[1
]}

Gu, X

VanLandingham, M

Nguyen, T

机构：

[1] Howard Univ, Dept Chem, Polymer Sci Div, Washington, DC 20059 USA

[2] Natl Inst Stand & Technol, Bldg & Fire Res Lab, Bldg Mat Div, Gaithersburg, MD 20899 USA

来源：

MACROMOLECULAR SYMPOSIA | 2001年 / 167卷

关键词：

D O I：

10.1002/1521-3900(200103)167:1<297::AID-MASY297>3.0.CO;2-2

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The mapping of chemically heterogeneous regions in PEA/PS film was achieved by reacting the film in a low pH environment and analyzing; by AFM. In 70:30 blend, the domains were identified as PS rich regions and matrix as the PEA rich regions, based on AFM images, FTIR measurements, and chemical modification study. During the course of hydrolysis of PEA, pits were formed in isolated regions of the matrix, as characterized by AFM.

引用

页码：297 / 305

页数：9

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