Crystal Structure and Luminescence of the [DyCl2(H2O)6]Cl Complex

被引：0
|
作者：
Bukvetskii, B. V. [1 ]
Mirochnik, A. G. [1 ]
Zhikhareva, P. A. [1 ]
机构：
[1] Russian Acad Sci, Inst Chem, Far East Div, Vladivostok 690022, Russia
来源：
OPTICS AND SPECTROSCOPY | 2020年 / 128卷 / 03期
关键词：
dysprosium(III); crystal structure; luminescence; WHITE-LIGHT EMISSION; YELLOW;
D O I：
10.1134/S0030400X20030054
中图分类号：
O43 [光学];
学科分类号：
070207 ; 0803 ;
摘要：
The crystal structure of the [DyCl2(H2O)(6)]Cl complex is studied by X-ray diffraction analysis. The crystals are constructed of complex cations [DyCl2(H2O)(6)](+) and outer-sphere Cl-1 ions. The structure is represented by separate [DyCl2(H2O)(6)] complexes bound by a dense network of \hydrogen bonds. The coordination polyhedron of Dy(III) with coordination number 8 is represented by a weakly distorted square antiprism. The results of investigation of the luminescent properties of the complex are presented.
引用
收藏
页码：323 / 326
页数：4
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