Isomerization of [In(H2O)3Cl3] · 18C6. Crystal structure of [mer-In(H2O)3Cl3] · 18C6 and [fac-In(H2O)3Cl3] · 18C6 · 2H2O

被引：0
|
作者：
A. B. Ilykhin
Zh. V. Dobrokhotova
S. P. Petrosyants
机构：
[1] Russian Academy of Sciences,Kurnakov Institute of General and Inorganic Chemisry
来源：
Russian Journal of Coordination Chemistry | 2008年 / 34卷
关键词：
Mass Loss; EtOH; 18C6; Crown Ether; Coordination Chemistry;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The complex [mer-In(H2O)3Cl3] · 18C6 (I) was isolated from the InCl3-H2O-Solv-18C6 solutions (Solv = MeOH, EtOH, THF). The second crystallization from mother solutions resulted in [fac-In(H2O)3Cl3] · 18C6 · 2H2O (II). The crystal and molecular structures of isomers I, II were identified by the powder X-ray diffraction, IR, and X-ray diffraction methods. Although complexes I, II have different compositions, they have the chain structure. The thermal decomposition of complexes I, II was studied.
引用
收藏
页码：641 / 646
页数：5
相关论文
共 50 条
  • [1] Isomerization of [In(H2O)3Cl3] • 18C6.: Crystal structure of [mer-In(H2O)3Cl3] • 18C6 and [fac-In(H2O)3Cl3] • 18C6 • 2H2O
    Ilykhin, A. B.
    Dobrokhotova, Zh. V.
    Petrosyants, S. P.
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2008, 34 (09) : 641 - 646
  • [2] Synthesis and structure of tin tetrachloride adducts with crown ether: Crystal structure of [Sn(H2O)2Cl4] • 18C6 and [Sn(H2O)2Cl4] • 18C6 • 2H2O
    Antsyshkina, A. S.
    Sadikov, G. G.
    Sevastyanov, V. G.
    Popov, V. S.
    Ignatov, P. A.
    Churakov, A. V.
    Simonenko, E. P.
    Kuznetsov, N. T.
    Sergienko, V. S.
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2011, 56 (04) : 530 - 538
  • [3] Synthesis and structure of tin tetrachloride adducts with crown ether: Crystal structure of [Sn(H2O)2Cl4] · 18C6 and [Sn(H2O)2Cl4] · 18C6 · 2H2O
    A. S. Antsyshkina
    G. G. Sadikov
    V. G. Sevastyanov
    V. S. Popov
    P. A. Ignatov
    A. V. Churakov
    E. P. Simonenko
    N. T. Kuznetsov
    V. S. Sergienko
    Russian Journal of Inorganic Chemistry, 2011, 56 : 530 - 538
  • [4] NOVYI GIDRATNYI IZOMER KHLORNOGO KHROMA [CR(H2O)3CL3].3H2O
    PREOBRAZHENSKII, BK
    LILOVA, OM
    ZHURNAL NEORGANICHESKOI KHIMII, 1963, 8 (03): : 779 - 780
  • [5] Scandium in a hydrochloric acid solution.: The crystal structure of ScCl3(H2O)3 • H2DA18C6 • Cl2 • 2H2O
    Petrosyants, SP
    Ilukhin, AB
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2003, 48 (09) : 1327 - 1333
  • [6] CRYSTAL-STRUCTURE OF [AS(C6H5)4]2[RE3CL11(H2O)].H2O
    JUNG, B
    MEYER, G
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1990, 45 (07): : 1097 - 1099
  • [7] Aggregates of the [GaCl4]- anion and the [Ga(H2O)3(NCS)3] complex with 18C6
    Petrosyants, S. P.
    Ilyukhin, A. B.
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2007, 33 (10) : 734 - 740
  • [8] Crystal structure and magnetic properties of [C6H4(CH2NH3)2][CuCl3(H2O)]Cl•H2O
    Haddad, SF
    Willett, RD
    Landee, CP
    INORGANICA CHIMICA ACTA, 2001, 316 (1-2) : 94 - 98
  • [9] Aggregates of the [GaCl4]− anion and the [Ga(H2O)3(NCS)3] complex with 18C6
    S. P. Petrosyants
    A. B. Ilyukhin
    Russian Journal of Coordination Chemistry, 2007, 33 : 734 - 740
  • [10] [Mn（H2O）4（NCS）2)（18C6）和(Co（H2O）4（NCS）2)（18C6）单晶的培养及物性表征
    杜高英
    张文兴
    樊悦朋
    高等学校化学学报, 1988, (08) : 764 - 768
12345