Isomerization of [In(H2O)3Cl3] · 18C6. Crystal structure of [mer-In(H2O)3Cl3] · 18C6 and [fac-In(H2O)3Cl3] · 18C6 · 2H2O

被引：0
|
作者：
A. B. Ilykhin
Zh. V. Dobrokhotova
S. P. Petrosyants
机构：
[1] Russian Academy of Sciences,Kurnakov Institute of General and Inorganic Chemisry
来源：
Russian Journal of Coordination Chemistry | 2008年 / 34卷
关键词：
Mass Loss; EtOH; 18C6; Crown Ether; Coordination Chemistry;
D O I：
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中图分类号：
学科分类号：
摘要：
The complex [mer-In(H2O)3Cl3] · 18C6 (I) was isolated from the InCl3-H2O-Solv-18C6 solutions (Solv = MeOH, EtOH, THF). The second crystallization from mother solutions resulted in [fac-In(H2O)3Cl3] · 18C6 · 2H2O (II). The crystal and molecular structures of isomers I, II were identified by the powder X-ray diffraction, IR, and X-ray diffraction methods. Although complexes I, II have different compositions, they have the chain structure. The thermal decomposition of complexes I, II was studied.
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页码：641 / 646
页数：5
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