Rate enhancement of Diels-Alder reactions in aqueous solutions

被引：16

作者：

Graziano, G ^{[1
]}

机构：

[1] Univ Sannio, Dipartimento Sci Biol & Ambientali, I-82100 Benevento, Italy

来源：

JOURNAL OF PHYSICAL ORGANIC CHEMISTRY | 2004年 / 17卷 / 02期

关键词：

Diels-Alder reaction; hydrophobic interactions; work of cavity creation; internal pressure;

D O I：

10.1002/poc.706

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

It is shown that the concept of internal pressure cannot be used to explain the strong rate enhancement of Diels-Alder reactions when carried out in water with respect to common organic solvents. Copyright (C) 2004 John Wiley Sons, Ltd.

引用

页码：100 / 101

页数：2

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