Rate enhancement of Diels-Alder reactions in aqueous solutions

被引：16
|
作者：
Graziano, G [1 ]
机构：
[1] Univ Sannio, Dipartimento Sci Biol & Ambientali, I-82100 Benevento, Italy
来源：
JOURNAL OF PHYSICAL ORGANIC CHEMISTRY | 2004年 / 17卷 / 02期
关键词：
Diels-Alder reaction; hydrophobic interactions; work of cavity creation; internal pressure;
D O I：
10.1002/poc.706
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
It is shown that the concept of internal pressure cannot be used to explain the strong rate enhancement of Diels-Alder reactions when carried out in water with respect to common organic solvents. Copyright (C) 2004 John Wiley Sons, Ltd.
引用
收藏
页码：100 / 101
页数：2
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