Two helical one-dimensional copper(II) coordination polymers based on N-(2-hydroxylbenzyl)glycine and N-(2-hydroxylbenzyl)-L-alanine:: Syntheses, crystal structures and magnetic studies

被引：17
|
作者：
Lü, ZL
Zhang, DQ [1 ]
Gao, S
Zhu, DB
机构：
[1] Chinese Acad Sci, Inst Chem, Organ Solids Lab, Beijing 100080, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Beijing 100080, Peoples R China
[3] Peking Univ, Coll Chem & Mol Engn, Beijing 100875, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2005年 / 8卷 / 08期
关键词：
helical chain; copper(II) complexes; crystal structure; amino acid; magnetic property;
D O I：
10.1016/j.inoche.2005.05.012
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two new helical Cu(II) coordination polymers, [Cu(2,2'-bpy)(Hsgly)]Cl center dot 2H(2)O(H(2)sgly = N-(2-hydroxylbenzyl)glycine) (1) and [Cu(2,2'-bpy)(HsaIa)](NO3) center dot 2H(2)O(H(2)sala = N-(2-hydroxylbenzyl)-L-alanine) (2) were synthesized. Single crystal X-ray diffraction analysis indicated that both complexes showed helical chains arrangement of Cu(II) centers bridged by carboxyl groups. The magnetic measurements showed complex 1 exhibited ferromagnetic interaction while there was no interaction between the Cu(II) centers in complex 2. (C) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码：746 / 750
页数：5
相关论文
共 50 条
  • [31] One-dimensional mercury(II) coordination polymers with a flexible bidentate Schiff base ligand (Me2N-Ba)2Bn: Synthesis, characterization, and crystal structures
    A. D. Khalaji
    B. Bahramian
    K. Jafari
    K. Fejfarova
    M. Dusek
    Russian Journal of Coordination Chemistry, 2013, 39 : 877 - 884
  • [32] Crystal structures and magnetic properties of tetranuclear copper(II) complexes of N-(2-hydroxymethylphenyl)salicylideneimine with a defective double-cubane core
    Koikawa, M
    Yamashita, H
    Tokii, T
    INORGANICA CHIMICA ACTA, 2004, 357 (09) : 2635 - 2642
  • [33] Syntheses, crystal structures and magnetic studies of new 2D coordination polymers containing dinuclear manganese(II) repetitive units using a ditopic isonicotinhydrazone based N,N,O-donor ligand
    Bikas, Rahman
    Hosseini-Monfared, Hassan
    Siczek, Milosz
    Gutierrez, Angel
    Krawczyk, Marta S.
    Lis, Tadeusz
    POLYHEDRON, 2014, 67 : 396 - 404
  • [34] Hydrothermal syntheses, crystal structures and physical properties of a new family of energetic coordination polymers with nitrogen-rich ligand N-[2-(1H-tetrazol-5-yl)ethyl]glycine
    Wang, Shuai-Hua
    Zheng, Fa-Kun
    Wu, Mei-Feng
    Liu, Zhi-Fa
    Chen, Jun
    Guo, Guo-Cong
    Wu, A-Qing
    CRYSTENGCOMM, 2013, 15 (14): : 2616 - 2623
  • [35] Copper(II) and nickel(II) coordination polymers assembled from 2,4-dibenzoylisophthalic acid and different N-donor co-ligands: syntheses, crystal structures, and magnetic properties
    Pang, Yu
    Tian, Dan
    Zhu, Xiao-Fei
    Luo, Yu-Hui
    Zheng, Xiang
    Zhang, Hong
    CRYSTENGCOMM, 2011, 13 (16): : 5142 - 5151
  • [36] Syntheses, crystal structures and magnetic properties of one-, two- and three-dimensional 2,2′-bipyrimidine-containing copper(II) complexes
    De Munno, G
    Poerio, T
    Julve, M
    Lloret, F
    Faus, J
    Caneschi, A
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1998, (10): : 1679 - 1685
  • [37] Syntheses, crystal structures and luminescent properties of two one-dimensional coordination polymers [CuX(dmpzm)]n (X = CN, NCS;: dmpzm = bis(3,5-dimethylpyrazolyl)methane)
    Xu, Y
    Ren, ZG
    Li, HX
    Zhang, WH
    Chen, JX
    Zhang, Y
    Lang, JP
    JOURNAL OF MOLECULAR STRUCTURE, 2006, 782 (2-3) : 150 - 156
  • [38] One-dimensional copper(II) coordination polymers built on 4′-substituted 4,2′:6′,4"- and 3,2′:6′,3"-terpyridines: Syntheses, structures and catalytic properties
    Li, Li
    Zhang, Yuan Zhuo
    Yang, Chengxiong
    Liu, E.
    Golen, James A.
    Zhang, Guoqi
    POLYHEDRON, 2016, 105 : 115 - 122
  • [39] Syntheses, structures and photoluminescence properties of two 2D Cd(II) coordination polymers based on a semirigid tridentate N-donor ligand
    Li, Jin-Hua
    Su, Bin
    Wang, Ji-Ping
    Wang, Guo-Ming
    Wang, Zong-Hua
    INORGANIC CHEMISTRY COMMUNICATIONS, 2017, 86 : 204 - 208
  • [40] {[Cu(mal)(bipy)]•2H2O}n:: a new one-dimensional ladder-like copper(II) complex based on the mixed N- and O-donor ligands with intrachain ferromagnetic interactions
    Zhang, KL
    Xu, Y
    Lin, JG
    You, XZ
    JOURNAL OF MOLECULAR STRUCTURE, 2004, 703 (1-3) : 63 - 67
12345