Two helical one-dimensional copper(II) coordination polymers based on N-(2-hydroxylbenzyl)glycine and N-(2-hydroxylbenzyl)-L-alanine:: Syntheses, crystal structures and magnetic studies

被引：17

作者：

Lü, ZL

Zhang, DQ ^{[1
]}

Gao, S

Zhu, DB

机构：

[1] Chinese Acad Sci, Inst Chem, Organ Solids Lab, Beijing 100080, Peoples R China

[2] Chinese Acad Sci, Grad Sch, Beijing 100080, Peoples R China

[3] Peking Univ, Coll Chem & Mol Engn, Beijing 100875, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2005年 / 8卷 / 08期

关键词：

helical chain; copper(II) complexes; crystal structure; amino acid; magnetic property;

D O I：

10.1016/j.inoche.2005.05.012

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two new helical Cu(II) coordination polymers, [Cu(2,2'-bpy)(Hsgly)]Cl center dot 2H(2)O(H(2)sgly = N-(2-hydroxylbenzyl)glycine) (1) and [Cu(2,2'-bpy)(HsaIa)](NO3) center dot 2H(2)O(H(2)sala = N-(2-hydroxylbenzyl)-L-alanine) (2) were synthesized. Single crystal X-ray diffraction analysis indicated that both complexes showed helical chains arrangement of Cu(II) centers bridged by carboxyl groups. The magnetic measurements showed complex 1 exhibited ferromagnetic interaction while there was no interaction between the Cu(II) centers in complex 2. (C) 2005 Elsevier B.V. All rights reserved.

引用

页码：746 / 750

页数：5

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