Post-synthetically modified metal-organic framework as a scaffold for selective bisulphite recognition in water

被引：18
|
作者：
Sen, Arunabha [1 ]
Desai, Aamod, V [1 ]
Samanta, Partha [1 ]
Dutta, Subhajit [1 ]
Leta, Sumanta [1 ]
Ghosh, Sujit K. [1 ,2 ]
机构：
[1] IISER, Dept Chem, Dr Homi Bhabha Rd, Pune 411008, Maharashtra, India
[2] IISER Pune, Ctr Energy Sci, Dr Homi Bhabha Rd, Pune 411008, Maharashtra, India
来源：
POLYHEDRON | 2018年 / 156卷
关键词：
Metal-organic framework; Post-synthetic modification; Sensing; Bisulfite ion; Turn-on; RATIOMETRIC FLUORESCENT-PROBE; TURN-ON PROBE; 1,4-ADDITION REACTION; SO2; DERIVATIVES; SULFUR-DIOXIDE; SULFITE; HYDROGEN; FUNCTIONALIZATION; LUMINESCENT; SEPARATION;
D O I：
10.1016/j.poly.2018.08.069
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A metal-organic framework (MOF) based luminescent probe was strategically designed for selective recognition of bisulfite anion (HS03) in water medium. The chemically stable MOF, NH2-MIL-68(In) was decorated with specific recognition site via post synthetic modification. The post synthetically modified MOF showed a selective turn on response towards bisulfite anion retaining its structural integrity. This selective recognition is also persistent even in presence of competing anions. (C) 2018 Elsevier Ltd. All rights reserved.
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页码：1 / 5
页数：5
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