Field calibration of a cluster of low-cost commercially available sensors for air quality monitoring. Part B: NO, CO and CO2

被引:231
|
作者
Spinelle, Laurent [1 ]
Gerboles, Michel [1 ]
Villani, Maria Gabriella [2 ]
Aleixandre, Manuel [3 ]
Bonavitacola, Fausto [4 ]
机构
[1] European Commiss, Joint Res Ctr, Directorate Energy Transport & Climate, Air & Climate Unit, Via Enrico Fermi 2749, I-21027 Ispra, VA, Italy
[2] Agenzia Nazl Nuove Tecnol Energia & Sviluppo Econ, ENEA, Ispra, VA, Italy
[3] CSIC, Inst Phys & Informat Technol, Madrid, Spain
[4] Phoenix Sistemi & Automaz Sagl, Muralto, TI, Switzerland
来源
关键词
Low-cost gas sensors; Validation; Measurement uncertainty; Multivariate linear regression; Artificial neural network; Air Quality Directive; GAS SENSORS; ARRAY; POLLUTION; PERFORMANCE; OZONE; QUANTIFICATION;
D O I
10.1016/j.snb.2016.07.036
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
In this work the performances of several field calibration methods for low-cost sensors, including linear/multi linear regression and supervised learning techniques, are compared. A cluster of either metal oxide or electrochemical sensors for nitrogen monoxide and carbon monoxide together with miniaturized infra-red carbon dioxide sensors was operated. Calibration was carried out during the two first weeks of evaluation against reference measurements. The accuracy of each regression method was evaluated on a five months field experiment at a semi-rural site using different indicators and techniques: orthogonal regression, target diagram, measurement uncertainty and drifts over time of sensor predictions. In addition to the analyses for ozone and nitrogen oxide already published in Part A [1], this work assessed if carbon monoxide sensors can reach the Data Quality Objective (DQOs) of 25% of uncertainty set in the European Air Quality Directive for indicative methods. As for ozone and nitrogen oxide, it was found for NO, CO and CO2 that the best agreement between sensors and reference measurements was observed for supervised learning techniques compared to linear and multilinear regression. (C) 2016 The Authors. Published by Elsevier B.V.
引用
收藏
页码:706 / 715
页数:10
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