Preparation of α,β-Unsaturated Diazoketones Employing a Horner-Wadsworth-Emmons Reagent

被引：29
|
作者：
Pinho, Vagner D. [1 ]
Burtoloso, Antonio C. B. [1 ]
机构：
[1] Univ Sao Paulo, Inst Quim Sao Carlos, BR-13560970 Sao Carlos, SP, Brazil
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2011年 / 76卷 / 01期
基金：
巴西圣保罗研究基金会;
关键词：
ARNDT-EISTERT SYNTHESIS; ALPHA; ACID; DIAZOMETHANE; INHIBITORS; CHLORIDE; AZIDES;
D O I：
10.1021/jo1021844
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A new method for the preparation of alpha,beta-unsaturated diazoketones from aldehydes and a Horner-Wadsworth- Emmons reagent is reported. The method was applied to the short synthesis of two substituted pyrrolidines.
引用
收藏
页码：289 / 292
页数：4
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