Preparation of α,β-Unsaturated Diazoketones Employing a Horner-Wadsworth-Emmons Reagent

被引：29

作者：

Pinho, Vagner D. ^{[1
]}

Burtoloso, Antonio C. B. ^{[1
]}

机构：

[1] Univ Sao Paulo, Inst Quim Sao Carlos, BR-13560970 Sao Carlos, SP, Brazil

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2011年 / 76卷 / 01期

基金：

巴西圣保罗研究基金会;

关键词：

ARNDT-EISTERT SYNTHESIS; ALPHA; ACID; DIAZOMETHANE; INHIBITORS; CHLORIDE; AZIDES;

D O I：

10.1021/jo1021844

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new method for the preparation of alpha,beta-unsaturated diazoketones from aldehydes and a Horner-Wadsworth- Emmons reagent is reported. The method was applied to the short synthesis of two substituted pyrrolidines.

引用

页码：289 / 292

页数：4

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